首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3581篇
  免费   606篇
  国内免费   122篇
电工技术   69篇
综合类   248篇
化学工业   1070篇
金属工艺   102篇
机械仪表   127篇
建筑科学   152篇
矿业工程   25篇
能源动力   27篇
轻工业   57篇
水利工程   18篇
石油天然气   25篇
武器工业   7篇
无线电   516篇
一般工业技术   533篇
冶金工业   329篇
原子能技术   46篇
自动化技术   958篇
  2023年   122篇
  2022年   25篇
  2021年   171篇
  2020年   177篇
  2019年   131篇
  2018年   168篇
  2017年   152篇
  2016年   163篇
  2015年   207篇
  2014年   253篇
  2013年   205篇
  2012年   176篇
  2011年   190篇
  2010年   137篇
  2009年   165篇
  2008年   152篇
  2007年   166篇
  2006年   171篇
  2005年   167篇
  2004年   136篇
  2003年   143篇
  2002年   135篇
  2001年   118篇
  2000年   89篇
  1999年   58篇
  1998年   71篇
  1997年   51篇
  1996年   46篇
  1995年   41篇
  1994年   27篇
  1993年   49篇
  1992年   28篇
  1991年   30篇
  1990年   30篇
  1989年   26篇
  1988年   9篇
  1986年   6篇
  1985年   8篇
  1984年   6篇
  1983年   6篇
  1982年   7篇
  1963年   5篇
  1961年   10篇
  1960年   5篇
  1959年   9篇
  1958年   7篇
  1957年   5篇
  1956年   7篇
  1955年   8篇
  1954年   5篇
排序方式: 共有4309条查询结果,搜索用时 218 毫秒
71.
随着电子客票和生物特征安检的发展,民航业务系统保存了大量旅客信息,这些信息为“智慧民航”发展奠定了数字基础,但同时也给民航的数据安全保护带来了新的挑战。为解决内部人员恶意或无意泄露旅客信息的情况,文章提出在内部人员访问旅客信息时,采用泛化FPE加密方式对旅客敏感信息进行实时脱敏,在保留旅客信息原始格式特征的基础上,确保旅客信息安全。实验结果表明,该方法可以高效、安全地处理旅客信息查询请求,从而在满足内部人员查询旅客信息的同时,保证旅客信息的安全。  相似文献   
72.
Cu/Al composites are of vital importance in industrial applications because of their numerous advantages. The influence of bond-ing temperature and cooling rate on the microstructure and morphology of ...  相似文献   
73.
针对智能教学系统中个性化教学序列生成规则难于获取的问题,提出了将案例推理技术应用于教学序列生成,设计了学生案例相似度的计算方法.为了在案例数量增大时获得较好的检索速度和命中率,提出通过关键属性聚类来对案例进行划分并设计了用于聚类的惰性2-中心点算法,最后以实例验证了系统设计的可用性.  相似文献   
74.
Castor oil (CO) is an environmentally friendly renewable green resource and ideal alternative to petroleum resources. The preparation of high strength and high toughness castor oil-based polyurethane prepolymer (COPU) composites has significant applications such as supporting material and engineering plastic sheet. In this study, unmodified clam shell powder (CSP) with a unique CaCO3-proteoglycan structure was used as a filler to prepare compatible reinforced COPU composite materials. Investigation of the mechanical properties revealed that the elastic modulus of the composite COPU reinforced with 50 wt% of CSP had increased to 5859.0 ± 8.4 MPa representing 187.77% to obtain stiffer and stronger material over pure COPU (2036.6 ± 196.9 MPa). Moreover, the scanning electron microscopy, thermogravimetric analysis and contact angle results demonstrated that the reinforced COPU composites have better compatibility, thermal stability, and water resistance than pure COPU. This work will promote the application prospects of CO-based polyurethane.  相似文献   
75.
In this work, low density hollow glass beads (HGB)/silicon rubber (SR) composites were prepared by solution method and flocculation process. The prepared samples were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, tensile test, and friction test. The results show that the densities of SR composites decrease from 1.140 to 0.792 g/cm3 with the addition of HGB. By comparing theoretical density with true density, it can be estimated that the ratio of shattered HGB increase from 8.79% to 24.76%. Especially, the mechanical properties of SR composites were improved by surface modification of HGB. By adding surface-modified HGB at 5 and 10 wt%, the tensile strengths of SR composites were enhanced by 17.8% and 28.2%, respectively. In addition, tear strength, shore A hardness, compression set, and friction property were significantly ameliorated. Furthermore, the mechanism of surface-modified HGB in mechanical properties was analyzed.  相似文献   
76.
Two kinds of bio-based polyurethane coatings for controlled-release urea were prepared by in-situ polymerization used castor oil and liquefied starch as raw materials, respectively. Scanning electron microscopy (SEM) showed that the section morphology of castor oil based polyurethane (Castor-PU) coating was uniform and dense, and that of liquefied starch based polyurethane (Starch-PU) coating had certain proportion of microporous. Infrared spectroscopy (IR) showed that the two coatings had typical urethane characteristic structure, but the difference was that the Starch-PU had obvious unreacted isocyanate structure. Differential scanning calorimetry (DSC) showed that the glass transition temperature of the two coatings was around 58°C, but the Castor-PU had a crystallization domain with obvious crystallization melting peak at 130°C. Thermogravimetric analysis (TG) showed that the thermal stability of Castor-PU was significantly higher than that of Starch-PU. The controlled-release property test showed that when the coating ratio was 2.8%, the nutrient release longevity of urea coated with Castor-PU was 49 days and that of urea coated with Starch-PU was 14 days. The reasons for the poor controlled-release performance of Starch-PU were analyzed, which probably caused by concentrated sulfuric acid and hydrophilic dispersant added in the liquefied starch.  相似文献   
77.
Owing to its high degree of crystallinity and orientation, the surface of aramid fiber is smooth, causing its low bonding strength with polymer matrix. This has restricted the application of aramid fiber in reinforced polymer materials. Effective methods are by introducing functional groups through surface modification and by increasing its surface roughness thereby greatly improving its bonding strength with the polymer. In this work, molecular dynamics (MD) simulation study fiber functionalized with hydroxyl (OH), carboxyl (COOH), and the silane coupling agent as nanofillers for polymer nanocomposites. The interfacial characteristics and the mechanical behavior of polymer nanocomposites are investigated. The results show that the functionalization can enhance the interfacial shear stress and tensile strength. The functional group not only provides a stronger interface, but also provides additional mechanical interlocking effect, which effectively improves load-bearing transmission capacity. The analysis of the micro-mechanism from the energy level also provides new insights for the functionalized design of nanocomposites.  相似文献   
78.
The modification of the surface characteristics after treatment with plasma in polymeric materials, such as the aging phenomenon, calls the attention of research in the area of nonthermal plasma technology. In this work, a direct treatment with dielectric-barrier discharge plasma was used on the surfaces of ultrafiltration membranes. The measurements of the contact angle with water, attenuated total reflectance accessory, zeta potential, atomic force microscopy and scanning electron microscopy-MEV were performed on the surfaces to verify changes after plasma treatment and to understand the occurrence and timing of the plasma aging effect. In the analysis of the membrane performance, hydraulic permeation and protein retention tests were performed. The results showed an improvement in wettability and hydrophilic properties in the post-treated membranes. The study of reversibility/aging of the post-plasma surface is important for research that deals with the modification of polymeric membranes. Changes in surface morphology, topography and wettability of the membranes were observed up to seven days after treatment, with a tendency to return to the initial characteristics of the membranes.  相似文献   
79.
In this work, Bis-(3-triethoxysilylpropyl) tetrasulphane was employed for surface modification of silica, ferrite and kenaf fiber filled natural rubber composites using aqueous solvent deposition, dry blending and integral blend methods. The efficiency of each method and the preferred modification method for improving the mechanical performance of natural rubber composites was assessed. The appearance of the Fourier transform infrared spectroscopy peak around 1088 cm−1 for all types of fillers provided evidence that silane interaction had occurred between the fillers and rubber and the formation of siloxane linkages were quantitatively determined by the crosslink density measurement. The surface treatment by dry method for silica and ferrite fillers showed significant improvement of tensile performance at approximately 67% and 34% compared to those with untreated fillers. For kenaf fiber-filled rubber composites, the surface treatment by aqueous solvent deposition showed the highest tensile improvement of 59% compared to the dry blending and integral blend method.  相似文献   
80.
High loadings of fillers are usually needed to achieve high-thermal conductivity (TC) of polymer-based composites, which inevitably sacrifices processability and meanwhile causes high-cost. Therefore, it is of great significance to achieve high-TC composites under low-filler loading. Here, a novel p-phenylenediamine (PPD) modified expanded graphite (EG-PPD)/epoxy (EP) composite with high TC and low-filler content was successfully prepared via pre-dispersion and vacuum assisted mixing strategy. With the improved interfacial compatibility between EG and EP by PPD, the prepared EG-PPD/EP composite exhibited excellent thermal management performance, resulting in the TC of which reached 4.00 W·m−1·K−1 with only 10 wt% (5.59 vol%) of EG-PPD, which is approximately 19 times higher than that of pure EP. Meantime, the interface thermal resistance of EG-PPD/EP composite between EG-PPD and EP is reduced by 33% compared with EG/EP composite. This composite with excellent TC property is expected to be used in thermal management field.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号